Необходимо зарегистрироваться, чтобы получить доступ к полным текстам статей и выпусков журналов!
- Название статьи
- ФУНДАМЕНТАЛЬНЫЕ УРАВНЕНИЯ СОСТОЯНИЯ о-м-п-КСИЛОЛОВ
- Авторы
- Александров Игорь Станиславович , стар. преподаватель кафедры ТГВ, Калининградский государственный технический университет, г. Калининград, Россия Тел. 8 (401) 266-11-58
Герасимов Анатолий Алексеевич , д-р техн. наук, проф., зав. кафедрой ТГВ, Калининградский государственный технический университет, г. Калининград, Россия Тел. 8 (401) 246-53-58
Григорьев Борис Афанасьевич , д-р техн. наук, проф., главный научный сотрудник, Институт проблем нефти и газа РАН, Москва, Россия Тел. 8 (401) 266-11-58
- В разделе
- ХИМИЯ. ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ. ХИМИЧЕСКАЯ ПРОМЫШЛЕННОСТЬ
- Ключевые слова
- орто-ксилол / мета-ксилол / пара-ксилол / уравнение состояния / температура / плотность / теплоемкость / энтальпия / скорость звука
- Год
- 2012 номер журнала 2 Страницы 48 - 62
- Индекс УДК
- УДК 536.71
- Код EDN
- Код DOI
- Тип статьи
- Научная статья
- Аннотация
- Разработаны фундаментальные уравнения состояния о-м-п-ксилолов, передающие с высокой точностью все термодинамические свойства в диапазоне температуры от тройной точки до начала термической деструкции (~ 700 K) при давлениях до 100 МПа. Средняя погрешность описания плотности составляет 0,1-0,3 %, давления насыщенного пара 0,1-0,3 %, изобарной теплоемкости 0,5-1,0 %, скорости звука 0,5-0,8 %.
- Полный текст статьи
- Необходимо зарегистрироваться, чтобы получить доступ к полным текстам статей и выпусков журналов!
- Список цитируемой литературы
-
Span R. Multiparameter Equation of State: An Accurate Source of Thermodynamic Property Data / R. Span. - Berlin: Springer, 2000. - 367 p.
Sun L., Ely J. E. Universal equation of state for engineering application: algorithm and application / L. Sun, J. E. Ely // Fluid Phase Equilibria. 2004. V. 222, 223. P. 107-118.
Marsh K. N. TRC Thermodynamic Properties of Substances in the Ideal Gas State / K. N. Marsh, R. C. Wilhoit, M. Frenkel et al. // Thermodynamics Research Center. 1994.
Ахундов Т. С.-А. Исследование теплофизических свойств углеводородов ароматического ряда: дис. …… д-ра тех. наук: 05.14.05 / Т. С.-А. Ахундов. - Баку, 1974. - 520 c.
Султанов Ч. И. Экспериментальное исследование изобарной теплоемкости пяти ароматических углеводородов в интервале температур 25-400 °С и давлений до 250 бар: дис. … канд. тех. наук: 05.14.05 /Ч. И. Султанов. - Баку, 1976. - 273 c.
Taravillo M. Equation of State of Liquid o-Xylene at Law Temperatures and High Pressures/M. Taravillo M., S. Castro, V. G. Baonza et al. // J. Chem. Soc. Faraday Trans. 1994. V. 90. No. 23. P. 3527-3532.
Taravillo M. Thermophysical Properties of Liquid m-Xylene at High Pressures/M. Taravillo, M. S. Castro, V. G. Baonza et al. // J. Chem. Soc. Faraday Trans. 1994. V. 90. No. 9. P.1217-1221.
Castro S. Thermodynamic Behaviour of Liquid p-Xylene Near Freezing/S. Castro, M. Taravillo, V. G. Baonza et al. // J. Chem. Soc. Faraday Trans. 1994. V. 90. No. 24. P. 3645-3649.
Chirico R. D. Thermodynamic Equilibria in xylene Isomerization. 3. The Thermodynamic Properties of o-Xylene/R. D. Chirico, S. E. Knipmeyer, A. Nguyen et al.//J. Chem. Eng. Data. 1997. V. 42. No. 4. P. 758-771.
Chirico R. D. V. Thermodynamic Equilibria in Xylene Isomerization. 2. The Thermodynamic Properties of m-Xylene/R. D. Chirico, S. E. Knipmeyer, A. Nguyen et al.//J. Chem. Eng. Data. 1997. V. 42. No. 3. P. 475-487.
Chirico R. D. V. Thermodynamic Equilibria in Xylene Isomerization. 1. The Thermodynamic Properties of p-Xylene/R. D. Chirico, S. E. Knipmeyer, A. Nguyen et al.//J. Chem. Eng. Data. 1997. V. 42. No. 2. P. 475-487.
Cibulka I. P-ρ-T Data of Liquids: Summarization and Evaluation. 5. Aromatic Hydrocarbons / I. Cibulka, T. Takagi // J. Chem. Eng. Data. 1999. V. 44. No. 3. P. 411-429.
Ambrose D. The Vapour Pressures above the Normal Boiling Point and the Critical Pressures of Some Aromatic Hydrocarbons / D. Ambrose, B. E. Broderick, R. Townsend//J. Chem. Soc. 1967. V. A. P. 633-641.
Ambrose D. Vapor Pressures of Some Aromatic Hydrocarbons / D. Ambrose // J. Chem. Thermodyn. 1987. V. 19. P. 1007.
Hessler W. Lichtenstein Sublimation Pressure Measurements on 1,4- and 1,2-dimethylbenzene and determination of the enthalpy of sublimation / W. Hessler // Wiss. Wilhelm-Pieck-Univ. Rostock. Naturwiss. Reie. 1986. V. 35. P. 27-33.
Александров И. С. Термические свойства ароматических углеводородов на линии насыщения / И. С. Александров, А. А. Герасимов // Известия КГТУ. 2010. № 18. С. 220-225.
Александров И. С. Энтальпия испарения и давление насыщенных паров н-алканов С5-С18 вблизи тройной точки/И. С. Александров, А. А. Герасимов, Е. Б. Григорьев //Оборонный комплекс - научно-техническому прогрессу России. 2010. № 4. С. 56-61.
Шойтов Ю. С. Зависимость скорости распространения звука в некоторых жидкостях от давления: дис. … канд. физ.-мат. наук: 01.04.14 / Ю. С. Шойтов. - Курск, 1972. - 158 c.
Hossenlopp I. A. Enthalpies of vaporization of piperidine and 1,2-dimethylbenzene; gas-phase isobaric heat capacities of piperidine / I. A. Hossenlopp, D. G. Archer // J. Chem. Thermodyn. 1988. V. 20. P. 1061-8.
Garg S. K. Heat capacities and densities of liquid o-xylene, m-xylene, p-xylene, and ethylbenzene, at temperatures from 318.15 K to 373.15 K and at pressures up to 10 MPa/S. K. Garg, T. S. Banipal, J. C. Ahlu-walia // J. Chem. Thermodyn. 1993. V. 25. P. 57-62.
Et-Tahir A. Determination of the viscosity of various hydrocarbons and mixtures of hydrocarbons versus temperature and pressure / A. Et-Tahir, C. Boned, B. Lagourette et al. // Int. J. Thermophys. 1995. V. 16. P. 1309-1334.
Pitzer K. S. The Thermodynamics and Molecular Structure of Benzene and Its Methyl Derivatives / K. S. Pitzer, D. W. Scott // J. Am. Chem. Soc. 1943. V. 65. P. 803.
Willingham C. B. Vapor Pressures and Boiling Points of Some Paraffin, Alkylcyclopentane, Alkylcyclohexane and Alkylbenzene Hydrocarbons / C. B. Willingham, W. J. Taylor, J. M. Pignocco et al. // J. Res. Natl. Bur. Stand. (U. S.). 1945. V. 35. P. 219-244.
Forziati A. F. Vapor Pressures and Boiling Points of Sixty API-NBS Hydrocarbons / A. F. Forziati, W. R. Norris, F. D. Rossini // J. Res. Natl. Bur. Stand. (U. S.). 1949. V. 43. P. 555-563.
Glaser F. Vapor Pressure Curves and Critical Data for Several Technically Important Organic Substances / F. Glaser, H. Ruland // Chem.-Ing.-Tech. 1957. V. 29. P. 772-775.
Nigam R. K. Excess Free Energies & Volume of Mixing for Methylene Chloride Mixtures with Benzene, Toluene, o-, m- & p-Xylenes & Cyclohexane / R. K. Nigam, B. S. Mahl // Indian J. Chem. 1971. V. 9. P. 1250.
Castellari C. Vapor-liquid equilibria in binary systems containing 1,3-di- oxolane at isobaric conditions: 3. binary mixtures of 1,3-dioxolane with o-, m- and p-xylenes / С. Castellari, R. Francesconi, F. Comelli // J. Chem. Eng. Data. 1982. V. 27. P. 156-158.
Rodrigues W. L. Vapor-Liquid Equilibria Data for Binary Systems of Ethylbenzene + Xylene Isomers at 100.65 kPa / W. L. Rodrigues, S. Mattedi, J. C. N. Abreu // J. Chem. Eng. Data. 2005. V. 50. P. 1134-1138.
Aucejo A. Isobaric Vapor-Liquid Equilibria for the Binary Mixtures of Styrene with Ethylbenzene, o-, m- and p-Xylene / A. Aucejo, S. Loras, V. Martinez-Soria et al. // J. Chem. Eng. Data. 2006. V. 51. P. 1051-1055.
Neubeck F. Molecular Volumes of Aromatic Compounds / F. Neubeck // Z. Phys. Chem., Stoechiom. Verwandtschaftsl. 1887. V. 1. P. 649-666.
Perkin W. H. LXIX. On Magnetic Rotatory Power, especially of Aromatic Compounds/W. H. Perkin// J. Chem. Soc. 1896. V. 69. P. 1025-1257.
Patterson T. S. The influence of solvents on the rotation of optically active compounds: III influence of benzene, toluene, o-Xylene, m-Xylene, p-Xylene, and mesitylene on the rotation of ethyl tartrate / T. S. Patterson // J. Chem. Soc. 1902. V. 81. P. 1097-1133.
Heil L. M. A determination of the total electric polarization and the electric moments of certain organic molecules / L. M. A Heil // Phys. Rev. 1932. V. 39. P. 666-674.
Massart L. Methods and apparatus in use at the bureau of physical-chemical scales: ix experimental research on the variation of density as a function of the temperature for a series of ten hydrocarbons / L. Massart// Bull. Soc. Chim. Belg. 1936. V. 45. P. 76.
Francis A. W. Pressure-Temperature-Liquid Density Relations of Pure Hydrocarbons/ A. W. Francis // Ind. Eng. Chem. 1957. V. 49. P. 1779.
Shraiber L. S. Temperature Variation of the Density of Certain Organic Liquids/L. S. Shraiber, N. G. Pe-chenyuk // Russ. J. Phys. Chem. (Engl. Transl.). 1965. V. 39. P. 219.
Hales J. L. Liquid densities from 293 to 490 K of nine aromatic hydrocarbons. / J. L. Hales, R. Townsend // J. Chem. Thermodyn. 1972. V. 4. No. 5. P. 763-772.
Hust J. G. Density and Crystallinity Measurements of Liquid and Solid n-Undecane, n-Tridecane and o-Xylene from 200 to 350 K / J. G. Hust, R. E. Schramm // J. Chem. Eng. Data. 1976. V. 21. P. 7-12.
Jain D. V. S. Excess molar heat capacities of binary mixtures of the isomeric xylenes at 303.65-321.65 K/ D. V. S. Jain, R. Chadha, S. K. Sehgal // Fluid Phase Equilibria. 1994. V. 96. P. 195-202.
Swain N. Viscosities, densities and excess properties of binary mixtures of di-(2-ethyl hexyl) phosphoric acid (DEHPA) with benzene, toluene and ortho-xylene / N. Swain, S. K. Singh, D. Panda et al. // J. Mol. Liq. 2001. V. 94. No. 3. P. 233-248.
Chen J. A study of densities and volumetric properties of binary mixtures of N-methyl-2-pyrrolidone with xylene at different temperatures and atmospheric pressure / J. Chen, R. Shen, W. Liu et al. // J. Chem. Thermodyn. 2007. V. 39. No. 6. P. 934-941.
Gonzalez-Olmos R. Influence of temperature on thermodynamics of ethers + xylenes / R. Gonzalez-Olmos, M. Iglesias // Fluid Phase Equilibria. 2008. V. 267. P. 133-139.
Song C.-Y. Densities and Viscosities of Binary Mixtures of Vitamin K3 with Benzene, Toluene, Ethylbenzene, o-Xylene, m-Xylene and p-Xylene from (303.15 to 333.15) K. / C.-Y. Song, H.-Z. Shen, J.-H. Zhao et al. // J. Chem. Eng. Data. 2008. V. 53. No. 5. P. 1110-1115.
Osborne N. S. Measurements of heat of vaporization and heat capacity of a number of hydrocarbons / N. S. Osborne, D. C. Ginnings // J. Res. Natl. Bur. Stand. 1947. V. 39. P. 453-477.
Cox J. D. The second viral coefficients of pyridine and benzene and some methyl homologues between 135 degrees and 165 degrees C / J. D. Cox, R. J. L. Andon // Trans. Faraday Soc. 1958. V. 54. P.1622-1629.
Williams J. W. The Specific Heats of Certain Organic Liquids at Elevated Temperatures / J. W. Williams, F. Daniels // J. Am. Chem. Soc. 1924. V. 46. P. 903-917.
Huffman H. M. Thermal Data on Organic Compounds: VII The Heat Capacities, Entropies and Free Energies of Twelve Aromatic Hydrocarbons. / H. M. Huffman, G. S. Parks, A. C. Daniels // J. Am. Chem. Soc. 1930. V. 52. P. 1547-1558.
Sastry N. V. Ultrasonic behaviour of methyl methacrylateqhydrocarbon mixtures at 298.15 and 308.15 K / N. V. Sastry, M. C. Patel, S. R. Patel // Fluid Phase Equilibria. 1999. V. 155. P. 261-276.
George J. Densities, Excess Molar Volumes at T = (298.15 to 313.15) K, Speeds of Sound, Excess Isentropic Compressibilities, Relative Permittivities and Deviations in Molar Polarizations at T = (298.15 and 308.15) K for Methyl Methacrylate + 2-Butoxyethanol or + Dibutyl Ether + Benzene, + Toluene and + p-Xylene / J. George, N. V. Sastry // J. Chem. Eng. Data. 2004. V. 49. P. 1116-1126.
Katyal R. C. Viscosities, Densities, and Ultrasonic Velocities of 3-Pentanone + Ethylbenzene and 3-Pentanone + o-Xylene at (293.15, 303.15 and 313.15) K / R. C. Katyal, S. Singh, V. K. Rattan et al. // J. Chem. Eng. Data. 2003. V. 48. No. 5. P. 1262-1265.
Al-Kandary J. A. Viscosities, Densities, and Speeds of Sound of Binary Mixtures of Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Mesitylene with Anisole at (288.15, 293.15, 298.15 and 303.15) K / J. A. Al-Kandary, A. S. Al-Jimaz, A.-H. M. Abdul-Latif // J. Chem. Eng. Data. 2006. V. 51. P. 2074-2082.
Chang J. S. Densities of m-Cresol + m-Xylene and m-Cresol + Tetralin Mixtures at 298-34-8 K and up to 30 MPa / J. S. Chang, M. J. Lee // J. Chem. Eng. Data. 1995. V. 40. P. 1115-1118.
Chang J. S. Densities of m-Xylene + Quinoline and m-Xylene + Tetralin from (333 to 413) K and up to 30 MPa / J. S. Chang, M. J. Lee, H. M. Lin // J. Chem. Eng. Data. 1996. V. 41. P. 1117-1120.
Caudwell D. R. Viscosity of Dense Fluid Mixtures: Doctorate of Philosophy Thesis; Imperial College, London, United Kingdom, 2004.
Park S. J. Isobaric Vapor-Liquid Equilibrium Data for the Binary Systems 1,3,5-Tri-methylbenzene/ N-Formylmorpholine and m-Xylene/N-Formylmorpholine / S. J. Park, J. Gmehling // J. Chem. Eng. Data. 1989. V. 34. P. 399.
Malanowski S. / S. Malanowski, B. Zegalska, B. Swiatek //Int. DATA Ser., Sel. Data Mixtures. 1994. Ser. A. V. 22. No. 4. P. 313 344.
Kremann R. Volume Change and Heats of Mixing for Binary Systems and Thermal Effects on Formation of Binary Mixtures / R. Kremann, R. Meingast, F. Gugl // Monatsh. Chem. 1914. V. 35. P. 1235.
Tyrer D. CCXXXVI. Adiabatic and Isothermal Compressibilities of Liquids between One and Two Atmospheres' Pressures / D. Tyrer // J. Chem. Soc. Trans. 1914. V. 105. P. 2534.
Azim M. A. XLVIII. Influence of Temp. on the Diamagnetism of Certain Liqiuids / M. A. Azim, S. S. Bhatnagar, R. N. Mathur // Philos. Mag. 1933. V. 16. P. 580.
Mathews J. H. The Accurate Measurement of Heats of Vaporization of Liquids / J. H. Mathews // J. Am. Chem. Soc. 1926. V. 48. P. 562-576.
Anthoney M. E., Carson A. S., Laye P. G.//J. Chem. Soc., Perkin Trans. 1976. V. 2. No. 9. P. 1032.
San Jose J. L. Measurement of the Isobaric Heat Capacity of Liquids and Certain Mixtures above the Normal Boiling Point/J. L. San Jose, G. Mellinger, R. C. Reid//J. Chem. Eng. Data 1976. V. 21. P. 414-417.
Paramo R. Saturated Heat Capacities of Some Linear and Branched Alkyl-Benzenes between 288 and 348 K. / R. Paramo, M. Zouine, M. C. Casanova // Int. J. Thermophys. 2003. V. 24. No. 1. P. 185-199.
Aralaguppi M. I. Excess molar volume, excess isentropic compressibility and excess molar refraction of binary mixtures of methyl acetoacetate with benzene, toluene, m-Xylene, mesitylene and anisole / M. I. Aralaguppi, T. M. Aminabhavi, R. H. Balundgi // Fluid Phase Equilibria. 1992. V. 71. P. 99-112.
Nain A. K. Ultrasonic and viscometric studies of molecular interactions in binary mixtures of tetrahydrofuran with some aromatic hydrocarbons at temperatures from 288.15 to 318.15 K / A. K. Nain // Phys. Chem. Liq. 2007. V. 45. No. 4. P. 371-388.
Yokoyama C. PVT relationships and solid-liquid equilibria for the m-Xylene-p-Xylene system under high pressures / C. Yokoyama, S. Moriya, S. Takahashi // Fluid Phase Equilibria. 1990. V. 60. P. 295-308.
Bich E. et al. // Phys. Chem. (Leipzig). 1981. V. 262. P. 402.
Osborn A. G. Vapor-Pressure Relations for 15 Hydrocarbons / A. G. Osborn, D. R. Douslin // J. Chem. Eng. Data. 1974. V. 19. P. 114-117.
Chianese A. Isobaric vapor-liquid equilibria of the ethylbenzene-p-xylene system / A. Chianese, L. Marrelli // J. Chem. Eng. Data. 1985. V. 30. P. 424.
Natarajan G. / G. Natarajan, D. S. Viswanath // J. Chem. Eng. Data. 1985. V. 30. P. 137-140.
Block H. Z. Phys. Chem., Stoechiom. Verwandschaftsl. 1912. V. 78. P. 385.
Jaeger F. M. Uber die Temperaturabhangigkeit der molekuran freien uberflackenenergie von flussigkeiten im temperaturbereich von -80 bis +1650/F. M. Jaeger//C. Z. Anorg. Allg. Chem. 1917. V. 101. P. 1-214.
Richards T. W. The Determination of Surface Tension with Very Small Volumes of Liquid, and the Surface Tensions of Octanes and Xylenes at Several Temperatures / T. W. Richards, C. L. Speyers, E. K. Carver// J. Am. Chem. Soc. 1924. V. 46. P. 1196-1207.
Timmermans J./ J. Timmermans, F. Martin //J. Chim. Phys. Phys.-Chim. Biol. 1926. V. 23. P. 747.
Yang C. Thermodynamic Properties of Binary Mixtures of p-Xylene with Cyclohexane, Heptane, Octane, and N-Methyl-2-pyrrolidone at Several Temperatures / C. Yang, W. Xu, P. Ma // J. Chem. Eng. Data. 2004. V. 49. P. 1794-1801.
Wang H. Excess volumes and partial molar volumes of binary mixtures of 1,2-propanediol carbonate with xylene in the temperature range of (293.15 to 353.15) K / H. Wang, L. Hu, Y. Wu // J. Chem. Thermodyn. 2005. V. 37. P. 1119-1129.
Di Z. Determination of Densities and Viscosities of p-Xylene-Acetic Acid-Water Ternary System / Z. Di, P. Ma, S. Xia et al. // PETROCHEMICAL TECHNOLOGY. 2006. V. 35. No. 9. P. 847-851.
Ott J. B. Excess volumes, enthalpies, and Gibbs free energies for mixtures of benzene + p-Xylene / J. B. Ott, J. R. Goates, R. B. Grigg // J. Chem. Thermodyn. 1979. V. 11. P. 1167-1173.
Messerly J. F. Condensed-phase heat capacities and derived thermodynamic properties 1,4-dimethyl-benzene, 1,2-diphenylethane, and 2,3-dimethylnaphthalene / J. F. Messerly, H. L. Finke, W. D. Good et al.// J. Chem. Thermodyn. 1988. V. 20. No. 4. P. 485-501.
Nath J. Ultrasonic Velocities in, and Adibatic Compressibilities for, Binary Liquid Mixtures of 1,2-Di-chloroethane with Benzene, Toluene, p-Xylene Quinoline and Cyclohexane / J. Nath, G. Singh // J. Chem. Eng. Data. 1986. V. 31. P. 327.
Kapoor S. Isobaric Vapor-Liquid Equilibria at 97.3 kPa and Excess Properties at (303.15, 308.15 and 313.15) K of Binary Mixture of p-Xylene + Decane / S. Kapoor, V. K. Rattan // J. Chem. Eng. Data. 2005. V. 50. No. 6. P. 1891-1896.
Kapoor S. Vapor-Liquid Equilibria and Excess Properties of the Binary System Vinyl Acetate + p-Xy-lene / S. Kapoor, V. K. Rattan // J. Chem. Eng. Data. 2005. V. 50. № 6. P. 1897-1901.
- Купить