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- Название статьи
- ТЕРМИЧЕСКИЕ СВОЙСТВА Н-АЛКАНОВ С5-С13 В ДИАПАЗОНЕ ТЕМПЕРАТУРЫ ОТ ТРОЙНОЙ ТОЧКИ ДО КРИТИЧЕСКОЙ
- Авторы
- Александров Игорь Станиславович , стар. преподаватель кафедры ТГВ, Калининградский государственный технический университет, г. Калининград, Россия Тел. 8 (401) 266-11-58
Герасимов Анатолий Алексеевич , д-р техн. наук, проф., зав. кафедрой ТГВ, Калининградский государственный технический университет, г. Калининград, Россия Тел. 8 (401) 246-53-58
Григорьев Евгений Борисович gba_41@mail.ru, д-р техн. наук, ведущий научный сотрудник, ФГУП "ВНИЦСМВ", Москва, Россия Тел. (498) 657-47-08
Григорьев Борис Афанасьевич gba_41@mail.ru, д-р техн. наук, профессор, главный научный сотрудник, Институт проблем нефти и газа Российской академии наук, Москва, Россия
- В разделе
- ФИЗИЧЕСКАЯ ХИМИЯ. ТЕРМОДИНАМИКА
- Ключевые слова
- нормальные алканы / давление насыщенного пара / плотность / энтальпия испарения / фактор сжимаемости / тройная точка / критическая точка
- Год
- 2011 номер журнала 1 Страницы 43 - 57
- Индекс УДК
- УДК 536.22
- Код EDN
- Код DOI
- Тип статьи
- Научная статья
- Аннотация
- Проведен критический анализ литературных данных о термических свойствах н-алканов С5-С13 на линии равновесия "жидкость-газ". На основе отобранных экспериментальных и расчетных данных разработаны эмпирические уравнения, описывающие давление насыщенного пара, плотность сосуществующих жидкой и газовой фаз в диапазоне температуры от тройной точки до критической. Средняя относительная погрешность описания упругости насыщенного пара составила 0,06-0,19 %; плотности жидкой фазы - 0,05-0,10 %; плотности газовой фазы - 0,20-0,30 %. Для ряда веществ представленные уравнения в указанном диапазоне температуры получены впервые.
- Полный текст статьи
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- Список цитируемой литературы
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