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- Article name
- Thermodynamic stationary states in solutions of chain molecules
- Authors
- VAINSHTEIN E. F., , , N. M. Emanuels Institute of Biochemical Physics of RAS, Moscow, Russia
- Keywords
- Year
- 2008 Issue 4 Pages 52 - 60
- Code EDN
- Code DOI
- Abstract
- Thermodynamic stationary states which arise in solution contained associates chain (oligomer and polymeric) molecules are considered. Location and/or number of weak (E/RT<1) intermolecular bond in thermodynamic stationary states and balanced state are differed. System exists in non same long-range (balanced) minimum of free energy. Different factors which exert influence on formation of thermodynamic stationary states are studied. It was established that such states arise in oligomers. With increase of molecular mass of chain molecules number of possible thermodynamic stationary states increase and ratio such states to number average molecular mass tend to constant quantity.
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